An amorphous Ge intermediate
layer is introduced into the Si bonded interface to lower the annealing
temperature and achieve good electrical characteristics. The interface and
electrical characteristics of n-Si/n-Si and p-Si/n-Si junctions manufactured by
low-temperature wafer bonding based on a thin amorphous Ge are investigated. It
is found that the bubble density tremendously decreases when the a-Ge film is
not immersed in DI water. This is due to the decrease of the −OH groups. In
addition, when the samples are annealed at 400 °C for 20 h, the bubbles totally
disappear. This can be explained by the appearance of the polycrystalline Ge
(absorption of H2) at the bonded interface. The junction resistance of the
n-Si/n-Si bonded wafers decreases with the increase of the annealing
temperature. This is consistent with the recrystallization of the a-Ge when
high-temperature annealing is conducted. The carrier transport of the Si-based
PN junction annealed at 350 °C is consistent with the trap-assisted tunneling
model and that annealed at 400 °C is related to the carrier recombination
model.
Source:IOPscience
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